Honestly, on LJ, you didn't even need to be that smart about HTML and coding. There were tutorials galore and at age sixteen-ish, I was making my own graphics and tweaking pre-made themes to suit my layout on my journal. Doesn't look like DW has gotten that far into it to have that as an option which is a shame, customizing themes was badass.
Depends on what you're looking for, tbh! I honestly don't know much about the way DW works with its coding, but there was a site I used for most basic HTML stuff (and honestly, that was sufficient for learning how to make tables for my icon posts or profile layout). I'll have to go see if it's still around lol
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